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Title: :  Study of antimicrobial activity of cyano hydrazone and their metal complexes
PaperId: :  25698
Published in:   International Journal Of Advance Research And Innovative Ideas In Education
Publisher:   IJARIIE
e-ISSN:   2395-4396
Volume/Issue:    Volume 11 Issue 1 2025
DUI:    16.0415/IJARIIE-25698
Licence: :   IJARIIE is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.

Author NameAuthor Institute
Dr shiv prasad singh uchchariaGovt. college joura Morena

Abstract

chemistry
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Hydrazones are a class of organic compounds with the structure R1R2C=N−NH2.[1] They are related to ketones and aldehydes by the replacement of the oxygen =O with the =N−NH2 functional group. They are formed usually by the action of hydrazine on ketones or aldehydes. Currently, we report the preparation of transition metal complexes Co(II), Ni(II), and Cu(II) of hydrazone Schiff base ligands, which are obtained by the condensation reaction of substituted salicylaldehyde and hydrazines. The synthesized hydrazone ligands and their metal complexes were characterized by spectroscopic methods such as Fourier transform infrared (FT-IR), UV–vis, nuclear magnetic resonance (1H NMR and C13 NMR), and mass spectrometry analyses. All of the quantum chemistry calculations were performed using DFT executed in the Gaussian 09 software package. The geometry was optimized by using the density functional theory (DFT) approximation at the B3LYP level with a basis set of 6-31G (d, p). There was excellent agreement between the FT-IR values obtained experimentally and those obtained theoretically for the test compounds. It is worth noting that none of the optimized geometries for any of the Schiff base and metal complexes had any eigenvalues that were negative, indicating that these geometries represent the true minimum feasible energy surfaces. We also analyzed the electrostatic potential of the molecule and NBO calculation at the same level of theory. Gauss View 6 was utilized for the file organization of the input data. Gauss View 6.0, Avogadro, and Chemcraft were used to determine the data. Additionally, synthesized compounds were screened for antimicrobial activity against Gram-negative bacteria (Salmonella typhi, Escherichia coli) and Gram-positive bacteria (Bacillus halodurans, Micrococcus luteus) and two fungal strains (Aspergillus flavus, Aspergillus niger). These research findings have established the potential of ligands and their metal complexes as antimicrobial agents. Additionally, the compounds demonstrated promising nonlinear optical (NLO) properties, with potential applications across a wide range of contemporary technologies.

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IJARIIE Dr shiv prasad singh uchcharia. "Study of antimicrobial activity of cyano hydrazone and their metal complexes" International Journal Of Advance Research And Innovative Ideas In Education Volume 11 Issue 1 2025 Page 721-726
MLA Dr shiv prasad singh uchcharia. "Study of antimicrobial activity of cyano hydrazone and their metal complexes." International Journal Of Advance Research And Innovative Ideas In Education 11.1(2025) : 721-726.
APA Dr shiv prasad singh uchcharia. (2025). Study of antimicrobial activity of cyano hydrazone and their metal complexes. International Journal Of Advance Research And Innovative Ideas In Education, 11(1), 721-726.
Chicago Dr shiv prasad singh uchcharia. "Study of antimicrobial activity of cyano hydrazone and their metal complexes." International Journal Of Advance Research And Innovative Ideas In Education 11, no. 1 (2025) : 721-726.
Oxford Dr shiv prasad singh uchcharia. 'Study of antimicrobial activity of cyano hydrazone and their metal complexes', International Journal Of Advance Research And Innovative Ideas In Education, vol. 11, no. 1, 2025, p. 721-726. Available from IJARIIE, http://ijariie.com/AdminUploadPdf/Study_of_antimicrobial_activity_of_cyano_hydrazone_and_their_metal_complexes_ijariie25698.pdf (Accessed : ).
Harvard Dr shiv prasad singh uchcharia. (2025) 'Study of antimicrobial activity of cyano hydrazone and their metal complexes', International Journal Of Advance Research And Innovative Ideas In Education, 11(1), pp. 721-726IJARIIE [Online]. Available at: http://ijariie.com/AdminUploadPdf/Study_of_antimicrobial_activity_of_cyano_hydrazone_and_their_metal_complexes_ijariie25698.pdf (Accessed : )
IEEE Dr shiv prasad singh uchcharia, "Study of antimicrobial activity of cyano hydrazone and their metal complexes," International Journal Of Advance Research And Innovative Ideas In Education, vol. 11, no. 1, pp. 721-726, Jan-Feb 2025. [Online]. Available: http://ijariie.com/AdminUploadPdf/Study_of_antimicrobial_activity_of_cyano_hydrazone_and_their_metal_complexes_ijariie25698.pdf [Accessed : ].
Turabian Dr shiv prasad singh uchcharia. "Study of antimicrobial activity of cyano hydrazone and their metal complexes." International Journal Of Advance Research And Innovative Ideas In Education [Online]. volume 11 number 1 ().
Vancouver Dr shiv prasad singh uchcharia. Study of antimicrobial activity of cyano hydrazone and their metal complexes. International Journal Of Advance Research And Innovative Ideas In Education [Internet]. 2025 [Cited : ]; 11(1) : 721-726. Available from: http://ijariie.com/AdminUploadPdf/Study_of_antimicrobial_activity_of_cyano_hydrazone_and_their_metal_complexes_ijariie25698.pdf
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