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Title: :  Pd (II) Catalytic Oxidation of L-Histidine by Cerium (IV) in Acidic Medium by Spectrophotometry Method
PaperId: :  22987
Published in:   International Journal Of Advance Research And Innovative Ideas In Education
Publisher:   IJARIIE
e-ISSN:   2395-4396
Volume/Issue:    Volume 10 Issue 2 2024
DUI:    16.0415/IJARIIE-22987
Licence: :   IJARIIE is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.

Author NameAuthor Institute
Gajanand SahuGovt. Nagarjuna P.G. College of Science, Raipur (C.G.)
Sanjay GhoshGovt. Nagarjuna P.G. College of Science, Raipur (C.G.)
Deepak SinhaGovt. Nagarjuna P.G. College of Science, Raipur (C.G.)
Vinod Kumar Jena Govt. Nagarjuna P.G. College of Science, Raipur (C.G.)
P.C.SharmaGovt. Nagarjuna P.G. College of Science, Raipur (C.G.)

Abstract

Chemical Kinetic
Keywords: Kinetics, Oxidation, L- Histidine, Cerium (IV), Pd(II), Sulphuric acid, KCl, Mechanism.
Abstract The rate of reaction of L-histidne with Ce (IV) acidic medium has been kinetically studied in the presence of Pd (II) as catalyst using a spectrometric method. The reactions have been performed at temperatures range from 298 K to 318 K in interval of 10 minutes. In the case of Ce (IV), this reaction would be a first order reaction. The results exhibits first order each in Ce (IV) and metal ion Pd(II) and positive fractional order with respect to [L-Histidine]. This would have a first order reaction between the Ce (IV) and L- histidine in the presence and absence SDS, CTAB and KCl. The rate constant decreases with increasing the concentration of [HSO4-] and [H+] ion. The thermodynamical parameter values such as ∆H#, ∆G# and ∆S# are increases with increaseing temperature. kobs = (kK[L-pro][Pd(II)])/(1+K[H^+ ][L-pro])

Citations

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IJARIIE Gajanand Sahu, Sanjay Ghosh, Deepak Sinha, Vinod Kumar Jena , and P.C.Sharma. "Pd (II) Catalytic Oxidation of L-Histidine by Cerium (IV) in Acidic Medium by Spectrophotometry Method" International Journal Of Advance Research And Innovative Ideas In Education Volume 10 Issue 2 2024 Page 1863-1876
MLA Gajanand Sahu, Sanjay Ghosh, Deepak Sinha, Vinod Kumar Jena , and P.C.Sharma. "Pd (II) Catalytic Oxidation of L-Histidine by Cerium (IV) in Acidic Medium by Spectrophotometry Method." International Journal Of Advance Research And Innovative Ideas In Education 10.2(2024) : 1863-1876.
APA Gajanand Sahu, Sanjay Ghosh, Deepak Sinha, Vinod Kumar Jena , & P.C.Sharma. (2024). Pd (II) Catalytic Oxidation of L-Histidine by Cerium (IV) in Acidic Medium by Spectrophotometry Method. International Journal Of Advance Research And Innovative Ideas In Education, 10(2), 1863-1876.
Chicago Gajanand Sahu, Sanjay Ghosh, Deepak Sinha, Vinod Kumar Jena , and P.C.Sharma. "Pd (II) Catalytic Oxidation of L-Histidine by Cerium (IV) in Acidic Medium by Spectrophotometry Method." International Journal Of Advance Research And Innovative Ideas In Education 10, no. 2 (2024) : 1863-1876.
Oxford Gajanand Sahu, Sanjay Ghosh, Deepak Sinha, Vinod Kumar Jena , and P.C.Sharma. 'Pd (II) Catalytic Oxidation of L-Histidine by Cerium (IV) in Acidic Medium by Spectrophotometry Method', International Journal Of Advance Research And Innovative Ideas In Education, vol. 10, no. 2, 2024, p. 1863-1876. Available from IJARIIE, https://ijariie.com/AdminUploadPdf/Pd__II__Catalytic_Oxidation_of_L_Histidine_by_Cerium__IV__in_Acidic_Medium_by_Spectrophotometry_Method_ijariie22987.pdf (Accessed : 29 August 2024).
Harvard Gajanand Sahu, Sanjay Ghosh, Deepak Sinha, Vinod Kumar Jena , and P.C.Sharma. (2024) 'Pd (II) Catalytic Oxidation of L-Histidine by Cerium (IV) in Acidic Medium by Spectrophotometry Method', International Journal Of Advance Research And Innovative Ideas In Education, 10(2), pp. 1863-1876IJARIIE [Online]. Available at: https://ijariie.com/AdminUploadPdf/Pd__II__Catalytic_Oxidation_of_L_Histidine_by_Cerium__IV__in_Acidic_Medium_by_Spectrophotometry_Method_ijariie22987.pdf (Accessed : 29 August 2024)
IEEE Gajanand Sahu, Sanjay Ghosh, Deepak Sinha, Vinod Kumar Jena , and P.C.Sharma, "Pd (II) Catalytic Oxidation of L-Histidine by Cerium (IV) in Acidic Medium by Spectrophotometry Method," International Journal Of Advance Research And Innovative Ideas In Education, vol. 10, no. 2, pp. 1863-1876, Mar-App 2024. [Online]. Available: https://ijariie.com/AdminUploadPdf/Pd__II__Catalytic_Oxidation_of_L_Histidine_by_Cerium__IV__in_Acidic_Medium_by_Spectrophotometry_Method_ijariie22987.pdf [Accessed : 29 August 2024].
Turabian Gajanand Sahu, Sanjay Ghosh, Deepak Sinha, Vinod Kumar Jena , and P.C.Sharma. "Pd (II) Catalytic Oxidation of L-Histidine by Cerium (IV) in Acidic Medium by Spectrophotometry Method." International Journal Of Advance Research And Innovative Ideas In Education [Online]. volume 10 number 2 (29 August 2024).
Vancouver Gajanand Sahu, Sanjay Ghosh, Deepak Sinha, Vinod Kumar Jena , and P.C.Sharma. Pd (II) Catalytic Oxidation of L-Histidine by Cerium (IV) in Acidic Medium by Spectrophotometry Method. International Journal Of Advance Research And Innovative Ideas In Education [Internet]. 2024 [Cited : 29 August 2024]; 10(2) : 1863-1876. Available from: https://ijariie.com/AdminUploadPdf/Pd__II__Catalytic_Oxidation_of_L_Histidine_by_Cerium__IV__in_Acidic_Medium_by_Spectrophotometry_Method_ijariie22987.pdf
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