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Title: :  Effect of Viscosity of cationic surfactants [tetradecyltrimethylammonium bromide (TTAB) and hexadeecyltrimethylammonium bromide (HTAB)] on Critical Micelle Concentration and Various Activation Parameters in (Methanol+ Water) and (Methanol+ Toluene) Systems
PaperId: :  15828
Published in:   International Journal Of Advance Research And Innovative Ideas In Education
Publisher:   IJARIIE
e-ISSN:   2395-4396
Volume/Issue:    Volume 8 Issue 1 2022
DUI:    16.0415/IJARIIE-15828
Licence: :   IJARIIE is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.

Author NameAuthor Institute
Dr. MayankMultanimal Modi College, Modinagar

Abstract

Chemistry
Viscosity, CMC, Micelles, Cationic surfactants, Fluidity, alcohol-water, alcohol-toluene system, activation parameters.
The viscosity (η) of cationic surfactants tetradecyltrimethylammonium bromide (TTAB) and hexadeecyltrimethylammonium bromide (HTAB) have been measured in both (methanol+ water) and (methanol+ Toluene) systems at different temperatures. The CMC values for TTAB in these systems at different temperature have been determined from the viscosity vs. concentration plots. The CMC values so obtained are in complete agreement with those obtained from conductance measurements. The values of molar volume and interaction coefficient have been evaluated from the Vand`s equation .The values of molar volume and interaction coefficient increase with increase in temperature and number of carbon atom in hydrophobic chain of the surfactant. The plots of [log η vs. 1/T] are found to be linear and the values of ∆H* have been calculated from the slopes of the linear plots. The values of ∆H* for methanol+10% toluene systems have been calculated. The values of ∆S* and ∆G* have been also calculated for the same systems from Eyring`s and Gibb`s equation respectively at 400C.Various activation parameters for fluidity of both the surfactants in methanol + water systems were also calculated.

Citations

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IJARIIE Dr. Mayank. "Effect of Viscosity of cationic surfactants [tetradecyltrimethylammonium bromide (TTAB) and hexadeecyltrimethylammonium bromide (HTAB)] on Critical Micelle Concentration and Various Activation Parameters in (Methanol+ Water) and (Methanol+ Toluene) Systems" International Journal Of Advance Research And Innovative Ideas In Education Volume 8 Issue 1 2022 Page 9-15
MLA Dr. Mayank. "Effect of Viscosity of cationic surfactants [tetradecyltrimethylammonium bromide (TTAB) and hexadeecyltrimethylammonium bromide (HTAB)] on Critical Micelle Concentration and Various Activation Parameters in (Methanol+ Water) and (Methanol+ Toluene) Systems." International Journal Of Advance Research And Innovative Ideas In Education 8.1(2022) : 9-15.
APA Dr. Mayank. (2022). Effect of Viscosity of cationic surfactants [tetradecyltrimethylammonium bromide (TTAB) and hexadeecyltrimethylammonium bromide (HTAB)] on Critical Micelle Concentration and Various Activation Parameters in (Methanol+ Water) and (Methanol+ Toluene) Systems. International Journal Of Advance Research And Innovative Ideas In Education, 8(1), 9-15.
Chicago Dr. Mayank. "Effect of Viscosity of cationic surfactants [tetradecyltrimethylammonium bromide (TTAB) and hexadeecyltrimethylammonium bromide (HTAB)] on Critical Micelle Concentration and Various Activation Parameters in (Methanol+ Water) and (Methanol+ Toluene) Systems." International Journal Of Advance Research And Innovative Ideas In Education 8, no. 1 (2022) : 9-15.
Oxford Dr. Mayank. 'Effect of Viscosity of cationic surfactants [tetradecyltrimethylammonium bromide (TTAB) and hexadeecyltrimethylammonium bromide (HTAB)] on Critical Micelle Concentration and Various Activation Parameters in (Methanol+ Water) and (Methanol+ Toluene) Systems', International Journal Of Advance Research And Innovative Ideas In Education, vol. 8, no. 1, 2022, p. 9-15. Available from IJARIIE, https://ijariie.com/AdminUploadPdf/Effect_of_Viscosity_of_cationic_surfactants_ijariie15828.pdf (Accessed : 31 January 2022).
Harvard Dr. Mayank. (2022) 'Effect of Viscosity of cationic surfactants [tetradecyltrimethylammonium bromide (TTAB) and hexadeecyltrimethylammonium bromide (HTAB)] on Critical Micelle Concentration and Various Activation Parameters in (Methanol+ Water) and (Methanol+ Toluene) Systems', International Journal Of Advance Research And Innovative Ideas In Education, 8(1), pp. 9-15IJARIIE [Online]. Available at: https://ijariie.com/AdminUploadPdf/Effect_of_Viscosity_of_cationic_surfactants_ijariie15828.pdf (Accessed : 31 January 2022)
IEEE Dr. Mayank, "Effect of Viscosity of cationic surfactants [tetradecyltrimethylammonium bromide (TTAB) and hexadeecyltrimethylammonium bromide (HTAB)] on Critical Micelle Concentration and Various Activation Parameters in (Methanol+ Water) and (Methanol+ Toluene) Systems," International Journal Of Advance Research And Innovative Ideas In Education, vol. 8, no. 1, pp. 9-15, Jan-Feb 2022. [Online]. Available: https://ijariie.com/AdminUploadPdf/Effect_of_Viscosity_of_cationic_surfactants_ijariie15828.pdf [Accessed : 31 January 2022].
Turabian Dr. Mayank. "Effect of Viscosity of cationic surfactants [tetradecyltrimethylammonium bromide (TTAB) and hexadeecyltrimethylammonium bromide (HTAB)] on Critical Micelle Concentration and Various Activation Parameters in (Methanol+ Water) and (Methanol+ Toluene) Systems." International Journal Of Advance Research And Innovative Ideas In Education [Online]. volume 8 number 1 (31 January 2022).
Vancouver Dr. Mayank. Effect of Viscosity of cationic surfactants [tetradecyltrimethylammonium bromide (TTAB) and hexadeecyltrimethylammonium bromide (HTAB)] on Critical Micelle Concentration and Various Activation Parameters in (Methanol+ Water) and (Methanol+ Toluene) Systems. International Journal Of Advance Research And Innovative Ideas In Education [Internet]. 2022 [Cited : 31 January 2022]; 8(1) : 9-15. Available from: https://ijariie.com/AdminUploadPdf/Effect_of_Viscosity_of_cationic_surfactants_ijariie15828.pdf
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